Angelina Jolie and Brad Pitt: 2009 Oscars Arrival

Ever the magnificent couple, Brad Pitt and Angelina Jolie made the red carpet walk at the Kodak Theatre on Sunday evening (February 22).

The "Mr and Mrs Smith" co-star couple arrived for the Academy Awards arm-in-arm, with Ang sporting a sexy Elie Saab gown while Brad rocked out his favorite Tom Ford tux.

At this year’s awards show, which is to be hosted by Hugh Jackman, top contenders include Oscar favorites Mickey Rourke, Kate Winslet, Penelope Cruz, Heath Ledger and the hit movie “Slumdog Millionaire”.

To see all of the action, tune into the 81st Academy Awards will be broadcast live at 8 p.m. ET on ABC.

Gossip Girls / Dailyfill.com

To see the entire gallery from the 2009 Academy Awards (February 22) - Click Here!